Volume : 08, Issue : 02, February – 2021

Title :

54.X-RAY DIFFRACTION STUDIES OF NEW HYDRAZONE SCHIFF BASE LIGAND AND DIVALENT Mn (II), Ni (II) AND Zn (II) COMPLEXES

Authors :

Gajanan Dongare

Abstract :

The divalent trivalent metal complexes of were synthesized by the reaction of new heterocyclic hydrazone Schiff base ligand of 4-(diethylamino)-2-hydroxybenzylidene)-4-oxopiperidine-1-carbohydrazide (H2L): The divalent metal (II) complex were spectrochemically analyzed viz., elemental analysis, Fourier Transform Infrared, Ultraviolet- visible spectroscopy, and X-ray diffraction. The ratio of stoichiometry of ligand with Mn(II), Ni(II) and Zn(II) ion were observed as 1:1 (M:L) in their complexes. On the basis of spectral data the complexes were suggested a octahedral structure to the Mn(II),Ni(II),Zn(II) ions.
KEYWORDS: Heterocyclic hydrazone, metal(II) complexes, spectrochemical analysis, X-ray diffraction.

Cite This Article:

Please cite this article in press Gajanan Dongare, X-Ray Diffraction Studies Of New Hydrazone Schiff Base Ligand And Divalent Mn (II), Ni (II) And Zn (II) Complexes., Indo Am. J. P. Sci, 2021; 08(02).

Number of Downloads : 10

References :

References :

[1]. Majumdar, P.; Pati, A.; Patra, M.; Behera, R. K.; Behera, A. K. Acid Hydrazides, Potent Reagents for Synthesis of Oxygen-, Nitrogen-, and/or Sulfur-Containing Heterocyclic Rings. Chemical Reviews 2014, 114 (5), 2942–2977. https://doi.org/10.1021/cr300122t.
[2]. Backes, G. L.; Neumann, D. M.; Jursic, B. S. Synthesis and Antifungal Activity of Substituted Salicylaldehyde Hydrazones, Hydrazides and Sulfohydrazides. Bioorganic and Medicinal Chemistry 2014, 22 (17), 4629–4636. https://doi.org/10.1016/j.bmc.2014.07.022.
[3]. Kashinath, K.; Durg, V.; Angadi, S. D. Synthesis , Characterization And Biological Activities Of Schiff Bases Derived From Hydrazide Derivative And Their Cu(II), Ni(II), Co(II), Zn(II), Cd(II) And Hg(II), Complexes. International Journal of Research in Pharmacy and Chemistry 2014, 4 (3), 557–563.
[4]. El-Gammal, O. A.; Abu El-Reash, G.; Ahmed, S. F. Synthesis, Spectral Characterization, Molecular Modeling and in Vitro Antibacterial Activity of Complexes Designed from O2, NO and NO Donor Schiff-Base Ligand. Spectrochimica Acta – Part A: Molecular and Biomolecular Spectroscopy 2015, 135, 227–240. https://doi.org/10.1016/j.saa.2014.04.197.
[5]. Ogunniran, K. O.; Adekoya, J. A.; Eromosele, C. O. E.-; Siyanbda, T. O.; Kayode, A.; Mesubi, M. A.; Narender, T. Transition Metal Complexes of (E)-N’-(4-Cyanobenzylidene)Nicotinohydrazide): Synthesis, Structural and Anti-Mycobacterial Activity Study. Journal of Applied Sciences 2015, 15 (10), 1210–1222. https://doi.org/10.3923/jas.2015.1210.1222.
[6]. Sukumarapillai, D. K.; Kooi-Yeong, K.; Kia, Y.; Murugaiyah, V.; Iyer, S. K. Design, Synthesis and Cholinesterase Inhibitory Evaluation Study of Fluorescent N-Benzylpiperidine-4-One Derivatives. Medicinal Chemistry Research 2016, 25 (8), 1705–1715. https://doi.org/10.1007/s00044-016-1619-6.
[7]. Karaman, N.; Oruç-Emre, E. E.; Sıcak, Y.; Çatıkkaş, B.; Karaküçük-İyidoğan, A.; Öztürk, M. Microwave-Assisted Synthesis of New Sulfonyl Hydrazones, Screening of Biological Activities and Investigation of Structure–Activity Relationship. Medicinal Chemistry Research 2016, 25 (8), 1590–1607. https://doi.org/10.1007/s00044-016-1592-0.
[8]. Mandewale, M. C.; Kokate, S.; Thorat, B.; Sawant, S.; Yamgar, R. Zinc Complexes of Hydrazone Derivatives Bearing 3,4-Dihydroquinolin-2(1H)-One Nucleus as New Anti-Tubercular Agents. Arabian Journal of Chemistry 2019, 12 (8), 4479–4489. https://doi.org/10.1016/j.arabjc.2016.07.016.
[9]. Shaabani, B.; Khandar, A. A.; Ramazani, N.; Fleck, M.; Mobaiyen, H.; Cunha-Silva, L. Chromium(III), Manganese(II) and Iron(III) Complexes Based on Hydrazone Schiff-Base and Azide Ligands: Synthesis, Crystal Structure and Antimicrobial Activity. Journal of Coordination Chemistry 2017, 70 (4), 696–708. https://doi.org/10.1080/00958972.2016.1274028.
[10]. Scharifi, E.; Danilenko, A.; Weidig, U.; Steinhoff, K. Influence of Plastic Deformation Gradients at Room Temperature on Precipitation Kinetics and Mechanical Properties of High- Strength Aluminum Alloys. Journal of Engineering Research and Application 2019, 9 (1), 24–29. https://doi.org/10.9790/9622.
[11]. Gundersen, E.; Fan, K.; Haas, K.; Huryn, D.; Jacobsen, J. S.; Kreft, A.; Martone, R.; Mayer, S.; Sonnenberg-Reines, J.; Sun, S. C.; Zhou, H. Molecular-Modeling Based Design, Synthesis, and Activity of Substituted Piperidines as γ-Secretase Inhibitors. Bioorganic and Medicinal Chemistry Letters 2005, 15 (7), 1891–1894. https://doi.org/10.1016/j.bmcl.2005.02.006.
[12]. Hostýnek, J. J.; Lauerma, A. I.; Magee, P. S.; Bloom, E.; Maibach, H. I. A Local Lymph-Node Assay Validation Study of a Structure-Activity Relationship Model for Contact Allergens. Archives of Dermatological Research 1995, 287 (8), 767. https://doi.org/10.1007/BF01105804.
[13]. Gajanan Dongare, Synthesis Of New Mononuclear Metal Complex Of Medicinal Significance From Hydrazone Schiff Base: Spectroscopic Characterization, And Antimicrobial Study, Indo Am. J. P. Sci, 2019; 06(04).
[14]. Gajanan Dongare et al., Synthesis Of Heterocyclic Hydrazone Schiff Base And Its Zn(II) Complex: Spectroscopic Characterization, XRD, Thermal, Antibacterial, And Antifungal Evaluation., Indo Am. J. P. Sci, 2019; 06[05].
[15]. Diab, M. A.; El-Sonbati, A. Z.; Morgan, S. M.; El-Mogazy, M. A. Polymer Complexes. LXXI. Spectroscopic Studies, Thermal Properties, DNA Binding and Antimicrobial Activity of Polymer Complexes. Applied Organometallic Chemistry 2018, 32 (8), 1–18. https://doi.org/10.1002/aoc.4378.
[16]. Emam, S. M.; Abouel-Enein, S. A.; Abdel-Satar, E. M. Structural Characterization, Thermal Investigation and Biological Activity of Metal Complexes Containing Schiff Base Ligand (Z)-3-(1-((4,6-Dimethyl-1H-Pyrazolo[3,4-b] Pyridin-3-Yl)Imino)Ethyl)-4-Hydroxy-6-Methyl-2H-Pyran-2-One. Applied Organometallic Chemistry 2019, 33 (5), 1–25. https://doi.org/10.1002/aoc.4847.
[17]. Wang, L.; Jin, P.; Huang, J.; She, H.; Wang, Q. Integration of Copper(II)-Porphyrin Zirconium Metal-Organic Framework and Titanium Dioxide to Construct Z-Scheme System for Highly Improved Photocatalytic CO2 Reduction. ACS Sustainable Chemistry and Engineering 2019, 7 (18), 15660–15670. https://doi.org/10.1021/acssuschemeng.9b03773.
[18]. Wang, L. H.; Qiu, X. Y.; Liu, S. J. Synthesis, Characterization and Crystal Structures of Copper(II), Zinc(II) and Vanadium(V) Complexes, Derived from 3-Methyl-N′-(1-(Pyridin-2-Yl)Ethylidene)Benzohydrazide, with Antibacterial Activity. Journal of Coordination Chemistry 2019, 72 (5–7), 962–971. https://doi.org/10.1080/00958972.2019.1590561.
[19]. Rahman, T.; Borah, G.; Gogoi, P. K. A Ligand Free Protocol Using Cu(OAc)2@Mont K-10 as Versatile Reusable Catalyst for Efficient Homocoupling of Arylboronic Acids for Synthesis of Symmetric Biaryls. Journal of the Indian Chemical Society 2018, 95 (7), 795–800.
[20]. de Paula, Q. A.; Joly, J. P.; Selmeczi, K.; Fonseca, D. E. P.; Caramori, G. F.; Farrell, N. P.; Da Costa Ferreira, A. M. Binding Affinity Studies of 1,2,3-Triazole Copper(II) Complexes to Human Serum Albumin. Journal of Coordination Chemistry 2018, 71 (11–13), 1894–1909. https://doi.org/10.1080/00958972.2018.1495331.
[21]. Mondal, I.; Chattopadhyay, S. Development of Multi-Metallic Complexes Using Metal-Salen Complexes as Building Blocks. Journal of Coordination Chemistry 2019, 72 (19–21), 3183–3209. https://doi.org/10.1080/00958972.2019.1695048.
[22]. Zhang, C.; Sutherland, M.; Herasymchuk, K.; Clarke, R. M.; Thompson, J. R.; Chiang, L.; Walsby, C. J.; Storr, T. Octahedral Co(III) Salen Complexes: The Role of Peripheral Ligand Electronics on Axial Ligand Release upon Reduction. Canadian Journal of Chemistry 2018, 96 (2), 110–118. https://doi.org/10.1139/cjc-2017-0277.
[23]. Biswas, N.; Bera, S.; Sepay, N.; Mukhopadhyay, T. K.; Acharya, K.; Ghosh, S.; Acharyya, S.; Biswas, A. K.; Drew, M. G. B.; Ghosh, T. Synthesis, Characterization, and Cytotoxic and Antimicrobial Activities of Mixed-Ligand Hydrazone Complexes of Variable Valence VO: Z + (z = 2, 3). New Journal of Chemistry 2019, 43 (42), 16714–16729. https://doi.org/10.1039/c9nj04171k.
[24]. Özdemir, Ö. Synthesis of Novel Azo Linkage-Based Schiff Bases Including Anthranilic Acid and Hexanoic Acid Moieties: Investigation of Azo-Hydrazone and Phenol-Keto Tautomerism, Solvatochromism, and Ionochromism. Turkish Journal of Chemistry 2019, 43 (1), 266–285. https://doi.org/10.3906/kim-1807-24.
[25]. Salah, B. A.; Kandil, A. T.; Abd El-Nasser, M. G. Synthesis, Molecular Docking and Computational Studies of Novel Hydrazone Complexes. Journal of Radiation Research and Applied Sciences 2019, 12 (1), 413–422. https://doi.org/10.1080/16878507.2019.1683273.
[26]. Pham, A. T.; Abbasi, P.; Monache, G. D.; Mazarakioti, E. C.; Rawson, J. M.; Stamatatos, T. C.; Pilkington, M. Magneto-Structural Studies of Two M–O–M Bridged Homochiral Mixed Valence Co(II)/Co(III) Complexes. Polyhedron 2019, 170, 34–40. https://doi.org/10.1016/j.poly.2019.05.026.